High Performance Electrocatalysts Based on Pt Nanoarchitecture for Fuel Cell Applications

Fuel cells, converting chemical energy from fuels into electricity directly without the need for combustion, are promising energy conversion devices for their potential applications as environmentally friendly, energy efficient power sources. However, to take fuel cell technology forward towards commercialization, we need to achieve further improvements in electrocatalyst technology, which can play an extremely important role in essentially determining cost-effectiveness, performance, and durability. In particular, platinum- (Pt-) based electrocatalyst approaches have been extensively investigated and actively pursued to meet those demands as an ideal fuel cell catalyst due to their most outstanding activity for both cathode oxygen reduction reactions and anode fuel oxidation reactions. In this review, we will address important issues and recent progress in the development of Pt-based catalysts, their synthesis, and characterization. We will also review snapshots of research that are focused on essential dynamics aspects of electrocatalytic reactions, such as the shape effects on the catalytic activity of Pt-based nanostructures, the relationships between structural morphology of Pt-based nanostructures and electrochemical reactions on both cathode and anode electrodes, and the effects of composition and electronic structure of Pt-based catalysts on electrochemical reaction properties of fuel cells.</jats:p

Critical Currents of Josephson-Coupled Wire Arrays

We calculate the current-voltage characteristics and critical current I_c^{array} of an array of Josephson-coupled superconducting wires. The array has two layers, each consisting of a set of parallel wires, arranged at right angles, such that an overdamped resistively-shunted junction forms wherever two wires cross. A uniform magnetic field equal to f flux quanta per plaquette is applied perpendicular to the layers. If f = p/q, where p and q are mutually prime integers, I_c^{array}(f) is found to have sharp peaks when q is a small integer. To an excellent approximation, it is found in a square array of n^2 plaquettes, that I_c^{array}(f) \propto (n/q)^{1/2} for sufficiently large n. This result is interpreted in terms of the commensurability between the array and the assumed q \times q unit cell of the ground state vortex lattice.Comment: 4 pages, 4 figure

Multiple Stellar Populations in the Globular Cluster omega Centauri as Tracers of a Merger Event

The discovery of the Sagittarius dwarf galaxy, which is being tidally disrupted by and merging with the Milky Way, supports the view that the halo of the Galaxy has been built up at least partially by the accretion of similar dwarf systems. The Sagittarius dwarf contains several distinct populations of stars, and includes M54 as its nucleus, which is the second most massive globular cluster associated with the Milky Way. The most massive globular cluster is omega Centauri, and here we report that omega Centauri also has several distinct stellar populations, as traced by red-giant-branch stars. The most metal-rich red-giant-branch stars are about 2 Gyr younger than the dominant metal-poor component, indicating that omega Centauri was enriched over this timescale. The presence of more than one epoch of star formation in a globular cluster is quite surprising, and suggests that omega Centauri was once part of a more massive system that merged with the Milky Way, as the Sagittarius dwarf galaxy is in the process of doing now. Mergers probably were much more frequent in the early history of the Galaxy and omega Centauri appears to be a relict of this era.Comment: 7 pages, 3 figures, Latex+nature.sty (included), To appear in November 4th issue of Natur

UV Bright Globular Clusters in M87: More Evidence for Super-helium-rich Stellar Populations?

We study the UV and optical properties of 38 massive GCs in M87, imaged using the HST/STIS and WFPC2 instruments. The majority of these GCs appear extremely bright in the FUV - roughly a magnitude brighter than their Galactic counterparts with similar metallicities. The observed FUV flux is several times larger than predictions of canonical old stellar population models. These canonical models, which assume a fiducial helium enrichment parameter, dY/dZ=2, are able to reproduce the observed FUV fluxes only if ages are 3--5 Gyr larger than the WMAP age of the Universe, although the same models fit the UV photometry of Galactic and M31 GCs for ages less than the WMAP age. A similar discrepancy is found between the mass-weighted and UV-luminosity weighted ages of the massive Galactic GC omega Cen, whose CMD (including peculiar features on its well-populated horizontal branch) can be accurately reproduced by invoking a small super-He-rich (dY/dZ ~ 90) stellar component. By comparison to omega Cen, we propose that the majority of M87 GCs in our sample contain strong signatures of similarly minor super-He-rich sub-components. Although we cannot prove or disprove the extreme helium scenario at the moment, we show that the same phenomenon that causes the extended horizontal branch of omega Cen explains the UV brightness of our sample. If this is indeed due to the extreme helium, this study would be the first to find its signatures in extragalactic objects.Comment: 19 pages, 10 figures, accepted for publication in MNRA

Characterization of a process for the in-furnace reduction of NOx, SO2, and HCl by carboxylic salts of calcium

Calcium magnesium acetate has been assessed as an agent for the reduction of NOx, SO2, and HCl, at the pilot scale, in a down-fired combustor operating at 80 kWth. In addition to this, the chemical and physical processes that occur during heating have been investigated. Benchmarking of calcium magnesium acetate with a suite of five other carboxylic salts (calcium magnesium acetate, calcium propionate, calcium acetate, calcium benzoate, magnesium acetate, and calcium formate) has been performed. NOx reduction involves the volatile organic content of the carboxylic salt being released at temperatures of >1000 °C, where the reaction of CHi radicals with NO under fuel-rich conditions can result in some of the NO forming N2 in a “reburning” process. Thermogravimetry-Fourier transform infrared (TG-FTIR) studies identified the nature of the decomposition products from the low- and high-temperature decompositions. In addition, the rate of weight losses were studied to investigate the influence of the organic decomposition on NOx reduction by reburning. In-furnace reductions of SO2 and HCl are aided by the highly porous, particulate residue, which results from the in situ drying, pyrolysis, and calcination processes. Simultaneous reduction of all three pollutants was obtained, and a synergy between SO2 and HCl capture was identified. A mechanism for this inter-relationship has been proposed. Sorbent particle characterization has been performed by collecting the calcined powder from a spray pyrolysis reactor and compared with those produced from a suite of pure carboxylic salts. Physical properties (including porosity, surface area, and decomposition behavior) have been discussed, relative to reductions in NOx and acid gas emissions

The Non-Destructive and Nano-Microstructural Characterization of Thermal-Barrier Coatings

The durability of thermal barrier coatings (TBCs) plays an important role in the service reliability and maintainability of hot-section components in advanced turbine engines for aerospace and utility applications. Photostimulated luminescence spectroscopy (PSLS) and electrochemical impedance spectroscopy (EIS) are being concurrently developed as complimentary nondestructive evaluation (NDE) techniques for quality control and liferemain assessment of TBCs. This paper discusses recent achievements in understanding the residual stress, phase constituents, and electrochemical resistance (or capacitance) of TBC constituents—with an emphasis on the thermally grown oxide. Results from NDE by PSLS and EIS are correlated to the nano- and microstructural development of TBCs

Role of extracellular DNA in Enterococcus faecalis biofilm formation and its susceptibility to sodium hypochlorite

Objective: This study investigated the role of extracellular deoxyribonucleic acid (eDNA) on Enterococcus faecalis (E. faecalis) biofilm and the susceptibility of E. faecalis to sodium hypochlorite (NaOCl). Methodology: E. faecalis biofilm was formed in bovine tooth specimens and the biofilm was cultured with or without deoxyribonuclease (DNase), an inhibitor of eDNA. Then, the role of eDNA in E. faecalis growth and biofilm formation was investigated using colony forming unit (CFUs) counting, eDNA level assay, crystal violet staining, confocal laser scanning microscopy, and scanning electron microscopy. The susceptibility of E. faecalis biofilm to low (0.5%) or high (5%) NaOCl concentrations was also analyzed by CFU counting. Results: CFUs and biofilm formation decreased significantly with DNase treatment (p&lt;0.05). The microstructure of DNase-treated biofilms exhibited less structured features when compared to the control. The volume of exopolysaccharides in the DNase-treated biofilm was significantly lower than that of control (p&lt;0.05). Moreover, the CFUs, eDNA level, biofilm formation, and exopolysaccharides volume were lower when the biofilm was treated with DNase de novo when compared to when DNase was applied to matured biofilm (p&lt;0.05). E. faecalis in the biofilm was more susceptible to NaOCl when it was cultured with DNase (p&lt;0.05). Furthermore, 0.5% NaOCl combined with DNase treatment was as efficient as 5% NaOCl alone regarding susceptibility (p&gt;0.05). Conclusions: Inhibition of eDNA leads to decrease of E. faecalis biofilm formation and increase of susceptibility of E. faecalis to NaOCl even at low concentrations. Therefore, our results suggest that inhibition of eDNA would be beneficial in facilitating the efficacy of NaOCl and reducing its concentration

The Non-Destructive and Nano-Microstructural Characterization of Thermal-Barrier Coatings

The durability of thermal barrier coatings (TBCs) plays an important role in the service reliability and maintainability of hot-section components in advanced turbine engines for aerospace and utility applications. Photostimulated luminescence spectroscopy (PSLS) and electrochemical impedance spectroscopy (EIS) are being concurrently developed as complimentary nondestructive evaluation (NDE) techniques for quality control and liferemain assessment of TBCs. This paper discusses recent achievements in understanding the residual stress, phase constituents, and electrochemical resistance (or capacitance) of TBC constituents—with an emphasis on the thermally grown oxide. Results from NDE by PSLS and EIS are correlated to the nano- and microstructural development of TBCs